Ligand-induced self-assembly of polyoxometalates
نویسندگان
چکیده
منابع مشابه
Spectroscopic readout of polyoxometalates' molecular information via self-assembly.
Polyoxometalates [SiM12O40](4-) (M = Mo(VI), W(VI)) and hemicyanine-derived chiral amphiphiles self-assemble in organic media where intermolecular interactions between POMs and hemicyanine units differ depending on the constituent metal ion species: this information is amplified to distinct spectral and self-assembling characteristics.
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The emergence of chirality is a central issue in chemistry, materials science, and biology. In nanoparticle assemblies, chirality has been shown to arise through a few different processes, but chiral organizations composed of plate-like nanoparticles, a class of material under scrutiny due to their wide applicative potential, have not yet been reported. We show that ribbons of stacked board-sha...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2017
ISSN: 2053-2733
DOI: 10.1107/s205327331708487x